Bis[μ-2-(2-benzoylhydrazinylidenemethyl)-6-methoxyphenolato][2-(2-benzoylhydrazinylidenemethyl)-6-methoxyphenolato]dimanganese(II) perchlorate methanol solvate
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چکیده
منابع مشابه
Bis[μ-2-(2-benzoylhydrazinylidenemethyl)-6-methoxyphenolato][2-(2-benzoylhydrazinylidenemethyl)-6-methoxyphenolato]dimanganese(II) perchlorate methanol solvate
In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa-hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O atoms from two ligands, and the other is coordinated by one N atom and five O atoms from three lig...
متن کامل2-[1-(2-Hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol methanol 1.13-solvate
In the main mol-ecule of the title compound, C(22)H(20)N(2)O(4)·1.13CH(4)O, the dihedral angles between the benzimidazole plane and the two benzene rings are 80.53 (10) and 82.76 (10)°. The solvent mol-ecules are disordered between three positions, with refined occupancies of 0.506 (13), 0.373 (13) and 0.249 (5). The crystal structure is stabilized by inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydr...
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In the title organic salt, C(18)H(14)N(3)O(+)·ClO(4) (-)·CH(4)O, there is a π-π stacking inter-action between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid-centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C-H bond and a symmetry-related pyridine ring. There are classical N-H⋯O ...
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The organic mol-ecule of the title compound, C(7)H(11)NO(4)S·CH(3)OH, is a zwitterion and its furan ring displays positional disorder [occupancy 0.563 (5):0.437 (5)]. The crystal structure is extended into a three-dimensional supra-molecular architecture through inter-molecular O-H⋯O and N-H⋯O hydrogen bonds with participation of the methanol solvent mol-ecules.
متن کاملBis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl-carbon-yl)pyridine-2-carboximidate (bpca) ligands and exhib-its a distorted octa-hedral coordination by six bpca N atoms. A classical O-H⋯O hydrogen bond exists between the methanol solvent mol-ecule and the perchlorate anion. Magnetic susceptibility measurements indica...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810018040